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Characterization of organic substrates bound to cross-linked polystyrenes by 13C NMR spectroscopy

✍ Scribed by Alan J. Jones; Clifford C. Leznoff; Polina I. Svirskaya

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 410 KB
Volume: 18
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270180414

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✦ Synopsis

Abstract

The ^13^C NMR spectra of a wide variety of organic substrates bound to 2% cross‐linked polystyrenes may be obtained routinely, provided the resins can be sufficiently swollen. The ^13^C chemical shifts of polymer‐bound trityl alcohol, polymer‐bound monotrityl ethers of the symmertrical diols HO (CH~2~)~n~OH (n=2, 4, 6, 7, 9 and 10), and some related intermediates in the solid phase synthesis of insect pheromones are presented. ^13^C shift additivity correlations, differing little from those in free trityl ethers, are drawn.

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