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Characterization of OH(ad) formation by reaction between H2O and O(ad) on Ag(110)

✍ Scribed by K. Bange; T.E. Madey; J.K. Sass

Publisher
Elsevier Science
Year
1985
Weight
44 KB
Volume
152-153
Category
Article
ISSN
0167-2584

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Surface-science simulation study of the
Surface-science simulation study of the electrochemical charge-transfer reaction (H)ad + (H2O)adβ†’(H3O+)ad + eβˆ’metal on Pt(111) and Cu(110)
✍ D. Lackey; J. Schott; J.K. Sass; S.I. Woo; F.T. Wagner πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 413 KB

By coadsorbing hydrogen and water on Pt( 111) and Cu( I lo), and isotopically substituting (H),.,by (D)ad, we have unambiguously identified the occurrence of the electrochemical reaction (H)ad+ (H\*O),,~(H,O+),+e,,,, in UHV. On Pt( I I1 ), a substantial fraction of the hydrogen is oxidized to (H,O+)