Characterization of nickel(II)-nickel(IV) linear chain compounds by nickel and chlorine K-edge EXAFS
โ Scribed by Evans, John; Gauntlett, J. Trevor; Levason, William
- Book ID
- 121428945
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 375 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
## Abstract In the Ni(II)โS(IV)โO~2~ system in the region of pH > 8.4, both Ni(II) and S(IV) are simultaneously autoxidized, and when sulfur is consumed fully NiOOH precipitates. At pH > 8.4, ethanol has no effect on the rate, whereas ammonia strongly inhibits the reaction when pH > 7.0. The kineti
The kinetics of electron transfer in the redox system containing phenylhydrazine (S) and tris(dimethylglyoximato)nickelate(IV), in the presence of catalytic amounts of added CU(&, have been studied in aqueous medium at an ionic strength of 0.25M in the pH range of 6.01-9.06. The kinetics exhibit pse