Characterization of Microporous Solids by Adsorption: Measurement of High-Resolution Adsorption Isotherms
β Scribed by Maglara, E.; Pullen, A.; Sullivan, D.; Conner, W. C.
- Book ID
- 127046229
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 726 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0743-7463
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π SIMILAR VOLUMES
Adsorption of binary ideal and nonideal liquid mixtures by heterogeneous micropore solids is discussed. Two equations for the filling of heterogeneous micropore liquid-solid systems, especially useful for strongly activated carbons, are derived by applying Dubinin's concept generalized by Stoeckli.
Argon adsorption isotherms measured at 77.5 K on various microporous activated carbons were analysed to characterize the structural heterogeneities of these sorbents. It was found that the adsorption isotherms could be described by an isotherm equation associated with the gamma micropore-size distri