Characterization of intramolecular charge-transfer transitions: 2,2-dicyanovinylaromatics

✍ Scribed by Jun-Ichi Aihara; Kotaro Araya; Kazuhiko Chiba; Yoshio Matsunaga

• Publisher: Elsevier Science
• Year: 1980
• Weight: 466 KB
• Volume: 18
• Category: Article
• ISSN: 0378-4487
• DOI: 10.1016/0378-4487(80)80050-1

✦ Synopsis

The first electronic transition energies of 2,2-dicyanovinylaromatics are linearly related to vertical ionization potentials of the parent aromatics. As in the case of binary charge-transfer complexes , this relationship gives a definite experimental support to the charge-transfer character of the electronic transitions concerned.