Characterization of functionally terminated polybutadienes of low molecular weight
✍ Scribed by Elie Ahad
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 482 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-8995
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High molecular weight carboxylated polybutadienes (cPBDs) with numberaverage molecular weight (M n ) from 98,000 to 200,000 and carboxylic acid (COOH) contents of 0.5-10 mol % were successfully synthesized through hydrocarboxylation of polybutadienes (PBDs) at temperatures of 140 -150°C using PdCl 2
## Abstract Acrolein was polymerized in a polar solvent in the presence of __terc__‐ and __sec__‐butyl lithium as initiators. Using a low monomer to initiator molar ratio and 1‐h reaction time, cyclic structures were shown to be formed in the main chain of the resulting oligomers. The influence of