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Characterization of biologically inactive spirolides E and F: Identification of the spirolide pharmacophore

✍ Scribed by Tingmo Hu; Jonathan M. Curtis; John A. Walter; Jeffrey L.C. Wright

Book ID
103406747
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
265 KB
Volume
37
Category
Article
ISSN
0040-4039

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## Abstract Synthesis of the DEF‐ring terpenoid fragment of terpendole E, an Eg5 inhibitor, is described. The DE‐ring was constructed by a modification of Barrero's radical cyclization. The F‐ring tetrahydropyran was then constructed by acid‐induced cyclization of an epoxy alcohol, which was prepar