Characterization of an intermediate in the reaction of a cationic carbonyl complex with secondary amine to give a carbamoyl complex
β Scribed by Huang, Li.; Ozawa, Fumiyuki.; Osakada, Kohtaro.; Yamamoto, Akio.
- Book ID
- 126820029
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 589 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0276-7333
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Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/chem.201100923. It contains full (analytical) details of catalytic experiments (gas-phase and H 2 O analysis), analysis of the possible reaction stoichiometries and simulation of the experimental results.
swurion me L ~L U J ~ rnar suoiimes auring rne reaction. in this way 1.4g (6.4mmol) of sublimed Cr(C0)6 and 1.8g (12.1 mmol) of ( I ) in lOml of dioxane were heated for about 36 h at the b. p. The unconsumed Cr(C0)6 was then removed from the cooled yellowish-brown solution by filtration, the dioxane