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Characterization of a Closed-Shell Fluorine−Fluorine Bonding Interaction in Aromatic Compounds on the Basis of the Electron Density

✍ Scribed by Matta, Chérif F.; Castillo, Norberto; Boyd, Russell J.


Book ID
120061500
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
531 KB
Volume
109
Category
Article
ISSN
1089-5639

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Electrochemical fluorination of aromatic
✍ Hirohide Horio; Kunitaka Momota; Katsuya Kato; Masayuki Morita; Yoshiharu Matsud 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 748 KB

The formation mechanism of 1,4\_difluorobenzene (5) has been studied during the electrolyses of chlorobenzene (l), I-chloro-4-fluorobenzene (2), bromobenzene (3) and 1-bromo-4-fluorobenzene (4) in Et,NF mHF. The mechanism consists of a cathodic dehalogeno-defluorination of 3-chloro-3,6,6trifluoro-1,