Characterization and superconductivity of YBa2Cu4O8 and Y2Ba4Cu7O14+x and their intergrowths
β Scribed by T. Graf; G. Triscone; A. Junod; J. Muller
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 887 KB
- Volume
- 165-166
- Category
- Article
- ISSN
- 0921-4526
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β¦ Synopsis
Pure single phase Y2Ba4Cu70l4+x ("247") and two phase compositions containing either "123" or "124" inclusions were prepared under 85 bar oxygen pressure at lOOOβ’C. The samples were characterized by X-ray diffraction, microprobe analysis and microstructural examination. The measurements of the a.c. susceptibility, the field cooling magnetization and the resistivity indicate that T c of "247" is actually higher than that of "124" but suggest a more pronounced influence of oxygen defects in "247" under the present conditions of synthesis.
π SIMILAR VOLUMES
The transition temperature of \(\mathrm{YBa}_{2} \mathrm{Cu}_{4} \mathrm{O}_{8}(124)\) is increased by about \(10 \mathrm{~K}\) by doping with calcium, whereas Ca substitution in \(\mathrm{Y}_{2} \mathrm{Ba}_{4} \mathrm{Cu}_{7} \mathrm{O}_{14+x}\) (247) has no effect on \(T_{\mathrm{c}}\). X-ray str
Various factors (orthorhombic strain, Cu-deficiency and Al-doping) which might be responsible for the disappearance of the plateau in the T~(x) dependence in YBa2CusO6+~ and YuBa4CuΒ’O14+~ are studied by Monte Carlo calculation of holes amount dependence on z in a framework of a generalized ASYNNNI m