Seeded emulsifier-free emulsion polymerization was used to prepare poly(styrene-co-acrylic acid) [P(St-co-AA)] microspheres. There are carboxyl groups on the surface of the P(St-co-AA) microspheres. Under appropriate conditions, the carboxyl react with NiCl 2 , etc., to form magnetic [P(St-co-AA)]Ni
Characterization and magnetic properties of P(St-co-4VP) metal microspheres
β Scribed by Yanmei Wang; Linxian Feng; Caiyuan Pan
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 175 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Monodispersed poly(styrene-co-4-vinylpyridine) [P(St-co-4VP)] microspheres were prepared by emulsifier-free emulsion polymerization. The chemical metal deposition was used to prepare magnetic P(St-co-4VP)Ni, and P(St-co-4VP)Co microspheres exhibited ferromagnetic properties. The morphology of P(St-co-4VP) and P(St-co-4VP)Ni or Co microspheres was studied by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Electron spectroscopy for chemical analysis (ESCA) and XRD were used to investigate the valence changement of metals in air. The magnetic properties of the magnetic microsphere were studied. The difference of soft magnetism between P(St-co-4VP)Ni and P(St-co-4VP)Co microspheres was discussed.
π SIMILAR VOLUMES
Emulsifier-free emulsion polymerization of styrene (St) and copolymerization of St and 4-vinyl pyridine (4VP) in the presence of ammonium persulfate were studied. A comparison between the two polymerization systems was made. It was found that there were big differences comparing polymerization rate,
Poly(styrene-co-methacrylic acid) P(St-co-MAA) microspheres with a monodisperse size distribution were prepared by emulsifier-free emulsion copolymerization of St and MAA. The effects of MAA content on the polymerization rate and the content of MAA in the copolymer were investigated by gravimetrical