Y zeolites with different sodium contents and a sodium mordenite were evaluated as support for bis(cyclopentadieny1)zirconium dichloride as catalyst for ethylene polymerization. The results showed that, although the activities of the supported catalysts were lower than that of the homogeneous system
Characterization and evaluation of supported rac-dimethylsilylenebis(indenyl)zirconium dichloride on ethylene polymerization
✍ Scribed by Fernando C. Franceschini; Tatiana T. da R. Tavares; Daniela Bianchini; Maria do Carmo M. Alves; Maria Lujan Ferreira; João H. Z. dos Santos
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 296 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Propene, 1‐butene and 1‐hexene polymerization was conducted with a mixture of __rac__‐ and __meso__‐[dimethylsilylenebis((2,3,5‐tetramethyl‐cyclopentadienyl))]zirconium dichloride (Me~2~Si(2,3,5‐Me~3~Cp)~2~ZrCl~2~) (1) combined with methylaluminoxane (MAO), triethylaluminium (AlEt~3~)/t
When characterized with DMA it was found that Phenylnorbornene-ethylene copolymers with equivalent comonomer concentrations had very different storage moduli in the glassy state as well as glass transition temperatures. NMR analysis of the copolymers revealed that they had different ratios of Exo-an