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Characterization and Electrochemical Properties of Molecular Icosanuclear and Bidimensional Hexanuclear Cu(II) Azido Polyoxometalates.

✍ Scribed by Celine Pichon; Pierre Mialane; Anne Dolbecq; Jerome Marrot; Eric Riviere; Bineta Keita; Louis Nadjo; Francis Secheresse

Publisher: John Wiley and Sons
Year: 2007
Weight: 23 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200736023

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✦ Synopsis

Abstract

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## Abstract Five Co^II^ silicotungstate complexes are reported. The centrosymmetric heptanuclear compound K~20~[{(B‐β‐SiW~9~O~33~(OH))(β‐SiW~8~O~29~(OH)~2~)Co~3~(H~2~O)}~2~Co(H~2~O)~2~]⋅47 H~2~O (1) consists of two {(B‐β‐SiW~9~O~33~(OH))(β‐SiW~8~O~29~(OH)~2~)Co~3~(H~2~O)} units connected by a {CoO~