Nickel-zeolite Y of various parent cation types, NiNa-A and NiNa-M were prepa'red. The reducibilities of nickel ions in these zeolites were evaluated by hydrogen consumption measurement. The nickel ions were reduced markedly by hydrogen in NiCa-Y, NiSr-Y and NiBa-Y in contrast to that of NiNa-Y, whe
Characterization and catalytic activity of nickel-zeolite catalysts. II. Effects of hydroxyl groups on reduction of nickel ions in mordenites
β Scribed by Minoru Suzuki; Kazuo Tsutsumi; Hiroshi Takahashi
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 627 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0144-2449
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β¦ Synopsis
A series of nickel, hydrogen-mordenites including various amounts of hydroxyl groups were prepared, and the effects of the hydroxyl groups on the degree of nickel reduction were studied. The reducibility of nickel ions decreased with the increase of acidic hydroxyl groups in mordenites. The effect of these hydroxyl groups was interpreted in terms of the reduction-oxidation characteristics of nickel ions in mordenites.
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A series of nickel-zeolite catalysts with alkaline earth, lanthanum and hydrogen ions as parent-cations in zeolite Y were prepared. The degrees of nickel ion reduction and the dispersion states of reduced nickel were affected by the extent of nickel-exchange and by the types of parent-cations in zeo
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