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Characteristics of the OH(OD) bands of methanol and ethanol in lithium salt—alcohol mixtures: saturated solutions and crystals

✍ Scribed by Jean Pierre Perchard

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 285 KB
Volume: 44
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80434-4

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✦ Synopsis

Ramnn Fpcctrn of alcohol (methanol, ethanol)-hthum sItIt (LCI, hRr, LC104) mixtures were examined. Results on 011 stretching bmds arc prescntcd for mtumtcd solutions at room tcrnpcraturc and for crystals obtained by cooling these solutions. In this second USC well defined compounds, of the hydmtc type. give rise to very narrow bands. showmg that the hydrogen atom posltlons xc ordered. For the C113OH--LtBr system, isotopic OH/OD ddutions lcad to the conchsion of B couphng between four 011 idcntkl vibrators, probably Furrounding one Br-amon.