Characteristics of the concentration ranges of existence of oscillations in the Belousov-Zhabotinskii reactions
✍ Scribed by A. S. Kovalenko; L. P. Tikhonova; O. M. Roizman; E. V. Protopopov
- Book ID
- 112362589
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 512 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-5760
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## Abstract A detailed chemical mechanism for the cerium catalyzed bromination and oxidation of malonic acid by bromate has been developed, and complete numerical solutions have been obtained for the temporal behavior of the concentrations of the intermediate species. The many points of similarity
Contrary to "classical" Belousov-Zhabotinskii (BZ) oscillatory systems, consisting of malonic acid, Ce (IV) -Ce (III) or Mn (III) -Mn (II) redox catalyst and KBrOa in solutions of H2SO4, where in an interval of added iodide initial concentrations 10 -4 mol din-3< [I-]o< 10 -a tool dm -3 the oscillal