Characteristics of a lithium secondary battery using chemically-synthesized conductive polymers
โ Scribed by Koji Nishio; Masahisa Fujimoto; Noriyuki Yoshinaga; Nobuhiro Furukawa; Osamu Ando; Hitoshi Ono; Tetsumi Suzuki
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 465 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0378-7753
No coin nor oath required. For personal study only.
โฆ Synopsis
Several conductive polymers (polyacetylene, polypyrrole, polythiophene, polyiminodibenxyl, polycarbaxole, polyfuran, polyphenothiaxine) have been synthesized by a chemical polymerization method and examin ed for their suitabiity as positive electrode material for lithium secondary batteries. A test cell, using polypyrrole as a positive electrode, showed good charge/discharge characteristics. Oxidixing agents for the synthesis of polypyrrole have been investigated for further improvement, and polypyrrole prepared by a new method of synthesis using a Cu(BF,),/nitrile system exhibited excellent performance.
๐ SIMILAR VOLUMES
Polypyrrole (PPy) deposited on a glass fibre separator was synthesized at room temperature by the vapour phase polymerization of pyrrole using FeC13 as an oxidant. The mechanism postulated for the oxidation reaction is based on inner-shell electron transfer. Lithium perchlorate dissolved in propylen
propylc~e ~r~onale solutlon as positi~ r for rte~argeable filhium batteries. Using t~ dee~mchemical m:asumm~, X-ray dJff~ct ~met~ and X-~y ~ho [o~]~g[rofi spearoscop~ ( E~A ), the ~o~si~e elea~de reaction with dischage and recharge issh~wnas~]~s:Nba\_~V~,(~.0.2-10}+n~++~r ~Li.Nbz ~V~Os, Tbedi~ha~e~a