Characterisation of some melamine-formaldehyde condensates and some cured resins by1H,13C and15N n.m.r. spectroscopy
โ Scribed by Ebdon, John R. ;Hunt, Barry J. ;O'Rourke, William T. S. ;Parkin, John
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1988
- Tongue
- English
- Weight
- 579 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0007-1641
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Pyridofuroxan ([1,2,5]oxodiazolo [3,4-b]pyridine 1-oxide) undergoes isomerization between the N1oxide and N3-oxide forms which can be observed by the 1 H, 13 C and 15 N NMR spectroscopy but not by 14 N and 17 O NMR at ambient and low temperatures. The rearrangement becomes slower at low temperatures
## Abstract ^13^C n.m.r. spectra of a series of __N__,__N__โdisubstituted thioamides have been recorded and signal assignments were performed. Separate signals are observed for methylene groups fixed on the nitrogen atom. Since the carbon atom __syn__ to the thiocarbonyl sulfur resonates at higher