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Changes in surface atomic ratio of ZrO2, SnO2and La2O3containing glass during alkali corrosion by X-ray photoelectron spectroscopy

✍ Scribed by Naoto Koshizaki

Publisher: Springer
Year: 1988
Tongue: English
Weight: 219 KB
Volume: 7
Category: Article
ISSN: 0261-8028
DOI: 10.1007/bf00720854

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📜 SIMILAR VOLUMES

Oxygen interaction of CdS-based gas sens

Oxygen interaction of CdS-based gas sensors with different stoichiometric compositions was studied by X-ray photoelectron spectroscopy (XPS) and thermal-desorption mass spectroscopy observations combined with conductivity measurements. Three different types of film with different atomic ratios of Cd/S were used in the study of oxygen chemisorption in a low-temperature range between 300 and 570 K. Spray pyrolysis was used for the deposition of the films on glass substrates; XPS and energy dispersive spectroscopy of X-ray together with atomic force microscopy and scanning electron microscopy were used for the characterization of the composition and structure of the films. It was possible to distinguish different temperature ranges for the thermal desorption of the different adsorbed oxygen species. A comparison of the data from XPS and mass-spectroscopy observations with conductance measurements allows to conclude that metallic surface atoms are responsible for different interactions of oxygen species with CdS surfaces.

📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 379 KB