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Change of Vibrational Energy into Rotational Energy in the Nitrogen Molecule

✍ Scribed by SHARMA, C. B.


Book ID
109647388
Publisher
Nature Publishing Group
Year
1966
Tongue
English
Weight
288 KB
Volume
209
Category
Article
ISSN
0028-0836

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πŸ“œ SIMILAR VOLUMES


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Vibrational deactivation probabiljties are caiculated for N2. Olr C12, I2 in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy I+ leased. even for the heaviest diatomics.

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Classical tujectory calculations for a model of 12 scattering from a surface show that in hi~h-xtergy collisions the amount of translational energy trancferred to rotation geatlv exceeds the amount transferred to vibration\_ The sudden approximation is used to qualitative& interpret the results.