Chain reaction mechanism of cellulose pyrolysis
โ Scribed by Pronoy K. Chatterjee
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 267 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
Chatterjee and Conrad1 studied the kinetics of pyrolysis of cotton cellulose in the temperature range 270-31OOC and proposed a chain reaction mechanism. Lipska and Parke? studied the pyrolysis of the a-cellulose in the temperature range 250-300ยฐC and interpreted the kinetic data differently. Both articles were published almost simultaneously. In this paper Lipska and Parker's complete data have been again analyzed and reinterpreted in light of the chain reaction mechanism. The energies of activation for initiation and propagation steps of the cellulose decomposition reaction are discussed.
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