Chain ion molecular mechanism of ascorbic acid oxidation with hydrogen peroxide. Cu3+ ion as a chain carrier

✍ Scribed by Yu. Skurlatov

• Book ID: 102929877
• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 997 KB
• Volume: 12
• Category: Article
• ISSN: 0538-8066
• DOI: 10.1002/kin.550120506

✦ Synopsis

The kinetics and mechanism of ascorbic acid (I)Hs) oxidation have been studied under anaerobic conditions in the presence ofCu"+ ions. At 5 ICu2+]o < 10-:'M, lo-" 5 IDHZIO < 10-"M, lo-? 5 IHrO,] < 0.1M, 3 5 pH < 4, the following expression for the initial rate of SKURLATOV (2) Cu:'+OH--