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Chain conformation of copoly(γ-methyl D, L-glutamate)

✍ Scribed by Yukio Musuda; Tatsuo Miyazawa; Murray Goodman

Publisher
Wiley (John Wiley & Sons)
Year
1969
Tongue
English
Weight
285 KB
Volume
8
Category
Article
ISSN
0006-3525

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✦ Synopsis

Synopsis

Copolymers of 7-methyl D-and L-glutamates with various D/L ratios were prepared. Infrared absorption spectra of solid films were measured and sums of right-and lefthanded helix contents were determined from intensities of amide V bands. Farultraviolet absorption spectra and optical rotatory dispersion of these copolymers ill solutions are used to ascertain their helical character. Chain conformations of DL- copolypeptides are discussed.

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