CH Hydroxylation Using a Heterocyclic Catalyst and Aqueous H2O2
✍ Scribed by Nichole D. Litvinas; Benjamin H. Brodsky; J. Du Bois
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 370 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Ni^II^(1,4,8,11‐tetraazacyclotetradecane)^2+^, Ni^II^L^2+^, is a good electrocatalyst for the oxidation of CH~3~NH~2~ and (CH~3~)~2~NH but not of (CH~3~)~3~N. The oxidation kinetics of the amines by Ni^III^L(H~2~O)~2~^3+^ indicate that the amines are good axial ligands to the tervalent