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CH Bond Activation Triggered by Formation of Metallacycles: Rhodium(I)-Catalyzed Cyclopropanation/Cyclization of Allenynes

✍ Scribed by Dr. Yoshihiro Oonishi; Yoshitaka Kitano; Prof. Dr. Yoshihiro Sato

Book ID
112001356
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
488 KB
Volume
51
Category
Article
ISSN
0044-8249

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Among numerous examples of transition-metal-mediated cyclization to obtain medium-sized ring compounds, [1] intramolecular hydroacylation provides the most promising way to prepare cyclopentanones from 4-pentenal through the CÀHbond activation of an aldehyde. [2, 3] However, its application has been