CH Bond Activation by Rhodium(I) Hydroxide and Phenoxide Complexes
✍ Scribed by Susan M. Kloek; D. Michael Heinekey; Karen I. Goldberg
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 88 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The reaction of [{RhCl(C~8~H~14~)~2~}~2~] (2) with __i__Pr~2~PCH~2~CH~2~C~6~H~5~ (L^1^) led, via the isolated dimer [{RhCl(C~8~H~14~)(L^1^)}~2~] (3), to a mixture of three products 4 a–c, of which the dinuclear complex [{RhCl(L^1^)~2~}~2~] (4 a) was characterized by Xray crystallography
Among numerous examples of transition-metal-mediated cyclization to obtain medium-sized ring compounds, [1] intramolecular hydroacylation provides the most promising way to prepare cyclopentanones from 4-pentenal through the CÀHbond activation of an aldehyde. [2, 3] However, its application has been