Metal Nitrosyl Reactivity: Acetonitrile-
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C. M. Frech; O. Blacque; H. W. Schmalle; H. Berke
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Article
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2006
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John Wiley and Sons
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English
⚖ 932 KB
## Abstract Treatment of the complexes [Re(NO)~2~(PR~3~)~2~][BAr^F^~4~] (R = Cy, 1 a; R = __i__Pr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C~6~H~5~)}(NO)~2~(PR~3~)~2~][BAr^F^~4~] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the cons