𝔖 Bobbio Scriptorium
✦   LIBER   ✦

C−H Activation of Acetonitrile at Nickel: Ligand Flip and Conversion of N-Bound Acetonitrile into a C-Bound Cyanomethyl Ligand

✍ Scribed by Oertel, Anna Magdalena; Ritleng, Vincent; Chetcuti, Michael J.; Veiros, Luis F.


Book ID
127067077
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
678 KB
Volume
132
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Metal Nitrosyl Reactivity: Acetonitrile-
✍ C. M. Frech; O. Blacque; H. W. Schmalle; H. Berke 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 932 KB

## Abstract Treatment of the complexes [Re(NO)~2~(PR~3~)~2~][BAr^F^~4~] (R = Cy, 1 a; R = __i__Pr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C~6~H~5~)}(NO)~2~(PR~3~)~2~][BAr^F^~4~] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the cons