CF2 emission during vacuum ultraviolet photodissociation of CF2Br2
β Scribed by Johnson, Christopher A. F.; Ross, Hilary J.
- Book ID
- 120315505
- Publisher
- The Royal Society of Chemistry
- Year
- 1978
- Weight
- 342 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0300-9589
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π SIMILAR VOLUMES
A transient absorption spectrum has been observed in the pulsed CO2 laser photodissociation of CFzBrz. This has been assigned to the intermediate CFsBr radical. The spectrum shows a broad band in the region of 220-320 nm with a maximum around 260 nm. The absorption cross section of CFzBr at 262 nm a
The CF (X) radical was generated by 248 nm excimer laser (Tp ~ 20 ns) photodissociation of gas-phase CF2Br2. The production of CF as a function of the photodissociation laser fluence β’ was monitored by laser-induced fluorescence (A 2y.+,.\_X 2I-1 ( 1, . . . . /lip 0) transition). The observed O dep