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Cetyltrimethylammonium-Selective PVC Electrode Based On Its Trinitrobenzene Sulfonate Ion-Pair

✍ Scribed by Y. M. Issa; S. S. Badawy; W. F. El-Hawary; M. S. Ashour

Book ID
101314505
Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
91 KB
Volume
11
Category
Article
ISSN
1040-0397

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Mechanistic aspects of the K+ ion select
Mechanistic aspects of the K+ ion selective electrode based on valinomycin-PVC
✍ R.D. Armstrong πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 355 KB

The mechanism of ion selective electrode membranes based on valinomycin+KBPh, in plasticized PVC is discussed in the light of recent impedance studies. In a typical membrane the K + is largely present as K+val -BPh, ion pairs. The transport number for K+val is -0.87 whilst that for BPh4 is -0.13. At