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Cesium hydroxide catalyzed addition of alcohols and amine derivatives to alkynes and styrene

โœ Scribed by Dimitrios Tzalis; Christopher Koradin; Paul Knochel

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
177 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

In the presence of catalytic amounts of cesium hydroxide (CsOH.H20), alcohols, substituted anilines and heterocyclic amines undergo an addition in NMP to phenylacetylene leading to functionalized enoi ethers and enamines. Anilines add to styrene (90-120ยฐC, 12-14 h) leading to N-substituted anilines in satisfactory yields.

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## Abstract For Abstract see ChemInform Abstract in Full Text.