Certified Reference Materials for Research in Antarctica: The Case of Marine Sediment
โ Scribed by S. Caroli; O. Senofonte; S. Caimi; P. Robouch; J. Pauwels; G.N. Kramer
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 68 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0026-265X
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โฆ Synopsis
The final product turned out to contain mostly particles smaller than 90 m (97% of total mass); particles larger than 150 m were practically absent. The fraction between 90 and 150 m comprised mainly organic material homogeneously distributed over the sediment. Five hundred two brown glass bottles (polyethylene insert and plastic screw cap; capacity 120 ml) could be thus filled with this material, each bottle containing about 75 g of the sediment. The certification project was accomplished with the active participation of eight internationally reputed laboratories from various countries (Belgium, Denmark, Hungary, Italy, Spain, and United States). The instrumental techniques resorted to in the certification exercise included cold vapor atomic absorption spectrometry, electrothermal atomization atomic absorption spectrometry, flame atomic absorption spectrometry, inductively coupled plasma atomic emission spectrometry, inductively coupled plasma mass spectrometry, isotope dilution inductively coupled plasma mass spectrometry, isotope dilution mass spectrometry, neutron activation analysis, solid sampling Zeeman electrothermal atomization atomic absorption spectrometry, and Zeeman electrothermal atomization atomic absorption spectrometry. The certified values established for some trace elements are as follows: Al, 67.1 ฯฎ 3.3 mg/g; As, 4.41 ฯฎ 1.06 g/g; Cd, 0.538 ฯฎ 0.027 g/g; Cr, 42.1 ฯฎ 3.4 g/g; Co, 6.87 ฯฎ 0.31 g/g; Fe, 24.4 ฯฎ 0.7 mg/g; Mn, 446 ฯฎ 19 g/g; Ni, 9.56 ฯฎ 1.05 g/g; Pb, 21.0 ฯฎ 2.9 g/g; Zn, 53.3 ฯฎ 2.7 g/g. In turn, additional elements were quantified by some participants. Homogeneity of the powdered sediment for the various analytes is such that intakes as low as 100 mg still show no deviation from the nominal values larger than the attached uncertainty. Intakes of 200 mg are, however, recommended to minimize any possible variations in concentration. The product has an average moisture content of 0.30 ฯฎ 0.03% on delivery.
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