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Cerimetric determination of oxygen balance in oxide superconductors

✍ Scribed by Josef Novák; Zuzana Málková; Zdena Pokorná; Věra Hamplová

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
271 KB
Volume
283
Category
Article
ISSN
0003-2670

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✦ Synopsis

This method is based on the oxidation of a known amount of iron(B) ions with oxide superconductors YElaCuO and BiSrCaCuO in a 2-5 mol 1-l solution of hydrobromic acid. The unreacted iron(B) ions were determined by cerimetric titration with ferroin as the indicator. This procedure allows the dissolution of samples even at elevated temperature. The reliability interval is 5%.

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