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Ceric ion-initiated polymerization of acrylonitrile in the presence of alcohols

✍ Scribed by Katai, A. A. ;Kulshrestha, V. K. ;Marchessault, R. H.


Book ID
105339705
Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
610 KB
Volume
2
Category
Article
ISSN
0449-2994

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πŸ“œ SIMILAR VOLUMES


A study on sorbitol-ceric ion initiated
✍ N. Mohanty; B. Pradhan; M.C. Mahanta πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 318 KB

The polymerization of acrylonitrile (M) initiated by the sorbitol (R)-C.e(IV) redox system has been studied in sulphuric acid in the range 30--40 Β° under nitrogen. At moderately high concentrations of Co(IV) (0.00015-0.02 M), the rate of polymerization (Rp) is proportional to [M'I s/2 and ['R'I j/2