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Ceric ammonium nitrate-initiated graft copolymerization of acrylamide onto Cassia tora gum

✍ Scribed by Brij Raj Sharma; Vineet Kumar; P. L. Soni


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
120 KB
Volume
86
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Graft copolymerization of acrylamide onto Cassia tora gum was studied in an aqueous medium using ceric ammonium nitrate‐nitric acid as the redox initiator. To optimize the reaction conditions for obtaining maximum percent grafting, the concentrations of Cassia tora gum, ceric ammonium nitrate, acrylamide, and nitric acid, time, and temperature were varied. Results are discussed and a reaction mechanism is proposed. Β© 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3250–3255, 2002


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The graft copolymerization of methyl acrylate onto sago starch was carried out by a free radical initiating process. The free radicals were produced by the chemical initiation method in which ceric ammonium nitrate was used as an initiator. It was found that the percentages of grafting, grafting eff