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Cercosporin, a Singlet Oxygen Generator

✍ Scribed by Ms. Diane C. Dobrowolski; Prof. Christopher S. Foote


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
218 KB
Volume
22
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Singlet oxygen generation from lophine h
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## Abstract Singlet oxygen was detected from the reaction of lophine hydroperoxides 2 in the presence of 1,3‐diphenyl‐isobenzofuran as a singlet oxygen detector. In order to examine the substituent effect on the formation of ^1^O~2~, 2‐(__p__‐substituted phenyl) lophine peroxides 2a–c were tested.

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Singlet oxygen ( 1 O 2 ) can be generated in a living cell upon focused laser irradiation of the intracellular photosensitizers. 1 O2 lifetime in the living cells is shortened by the reactions with cellular molecules, and thus the 1 O2 diffusion in a single cell has attracted much attention. In this

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Singlet oxygen generation is reported from (1) enzymatic reaction and (2) electron transfer reactions of the superoxide anion measured directly with an ultrasensitive near-IR emission spectrophotometer by monitoring the Oz('A,) + O2 (32,-) transition at 1268nm. Near-IR emission spectra from the myel