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CeCl3-Promoted Asymmetric Cycloaddition of Isocyanates with 2-Vinylaziridines.

✍ Scribed by Chune Dong; Howard Alper


Publisher
John Wiley and Sons
Year
2004
Weight
117 KB
Volume
35
Category
Article
ISSN
0931-7597

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Theoretical Studies on Cycloaddition Rea
✍ Si-Ya Yang; Cheng-Ke Sun; De-Cai Fang πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 204 KB πŸ‘ 2 views

## Abstract The mechanisms of cycloaddition reactions between 2‐azaallene cations and isocyanates have been explored at the B3LYP/6‐31G\* level. It is found that [2+2] or [2+4] cycloaddition reactions can take place via an intermediate when 2‐azaallene cations react with 1 or 2 equiv. of isocyanate