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Ce4O4S3: A Mixed-Valence Cerium Oxide Sulfide

✍ Scribed by Dr. Winfried Wichelhaus

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
232 KB
Volume
17
Category
Article
ISSN
0044-8249

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✦ Synopsis

The first oxide sulfide of rate earth metals to contain M^3+^ and M^4+^ ions is CeCeO~4~S~3~. The compound is a semiconductor and has M^3+^ and M^4+^ in two crystallographically distinct positions.

πŸ“œ SIMILAR VOLUMES

Structure and bonding in cerium oxysulfi
Structure and bonding in cerium oxysulfide compounds. IIIβ€”Electronic, infrared and resonance Raman spectra of and lattice dynamics calculations on mixed-valence Ce4O4S3
✍ C. Sourisseau; R. Cavagnat; M. Fouassier; R. Mauricot; M. Evain πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 446 KB πŸ‘ 2 views

The electronic (350-900 nm), infrared and Raman (700-30 cm-1) spectra of polycrystalline samples of the mixedvalence (Ce3'/Ce4') oxysulÐde compound were investigated. The compound is a low-gap semiconductor Ce 4 O 4 S 3 with intervalence transitions in the near-infrared (ca. 850 nm) and visible (ca.

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ChemInform Abstract: Pseudotetragonal Structure of Li2+xCex3+Ce12-x4+F50: The First Mixed Valence Cerium Fluoride.
✍ Guillaume Renaudin; Belto Dieudonne; Daniel Avignant; Elise Mapemba; Malika El-G πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v