Ce3+ as a probe of the crystal field and the nature of the impurity-ligand bond in borate and phosphate glasses

✍ Scribed by Renata Reisfeld; J. Hormodaly; Baruch Barnett

• Publisher: Elsevier Science
• Year: 1972
• Tongue: English
• Weight: 348 KB
• Volume: 17
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(72)87066-0

✦ Synopsis

From the optical absorption specirum of Cc '+ in borate and phosphate glasses, WC calculate the ncphehuxetic effect in the 4f-5d transition and the crystal field strength in these hosts. Some effects of cavalency on the C@-&and bond are discussed and the bond-forming f-orbit& suggested.