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CCLXXV.?The isomerism of the styryl alkyl ketones. Part I. The isomerism of 2-hydroxystyryl methyl ketone

✍ Scribed by McGookin, Alexander; Heilbron, Isidor Morris

Book ID
120992649
Publisher
The Royal Society of Chemistry
Year
1924
Tongue
English
Weight
464 KB
Volume
125
Category
Article
ISSN
0368-1645

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πŸ“œ SIMILAR VOLUMES

The Thermal Isomerizations of Bicyclo[2.
The Thermal Isomerizations of Bicyclo[2.1.0]pent-5-yl Methyl Ketones: endo-exo stereomutation and cyclopropyl-allylic rearrangement to cyclopent-2-enyl methyl ketones
✍ Jean-Pierre Grosclaude; Hans-Ulrich Gonzenbach; Jean-Claude Perlberger; Kurt Sch πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 650 KB

## Abstract Bicyclo[2.1.0]pent‐5‐yl methyl ketones undergo two thermal isomerization reactions. The __endo‐exo__ stereomutation follows the ring‐flip path in better than 90%, with inversion of the configuration of the angular carbon atoms by cleavage and reclosure of the central bond. Stereomutatio