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CCCCIII.—The Reimer–Tiemann reaction with m-bromo- and m-iodo-phenol

✍ Scribed by Hodgson, Herbert Henry ;Jenkinson, Thomas Alfred

Book ID
118170470
Publisher
The Royal Society of Chemistry
Year
1927
Weight
246 KB
Volume
0
Category
Article
ISSN
0368-1769

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Theoretical investigation of the abnorma
Theoretical investigation of the abnormal Reimer–Tiemann reaction
✍ R. Castillo; V. Moliner; J. Andrés; M. Oliva; V. S. Safont; S. Bohm 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 361 KB

The molecular mechanism for the pyrrole ring expansion to yield 3-chloropyridine, as a model of the abnormal Reimer-Tiemann rearrangement, was characterized theoretically in vacuo by means of the HF/6-31G\* computational method. The electron correlation was estimated at the MP2/6-31G\* level and by