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C−C Coupling Reactions of Aryl Bromides and Arylsiloxanes in Water Catalyzed by Palladium Complexes of Phosphanes Modified with Crown Ethers

✍ Scribed by Gordillo, Álvaro; de Jesús, Ernesto; López-Mardomingo, Carmen

Book ID: 121286214
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 89 KB
Volume: 8
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol061221y

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## Abstract The crown ether phosphanes PAr\*Ph~2~ (1) and PAr\*~2~R [Ar\* = 3,4‐(18‐crown‐6)‐phenyl; R = Me (2); R = Ph (3)], prepared from PCl~2~R and Ar\*Li, have been studied. The syntheses and characterization of their oxides (4–6), and their BH~3~ (7–9), PdCl~2~ (10–12), and PtCl~2~ (13–15) co