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[Ca(XeF2)n](AsF6)2: (n=4, 2.5): the first coordination compounds of Ca2+ with XeF2 ligand

✍ Scribed by Primož Benkič; Melita Tramšek; Boris Žemva

Book ID: 114370500
Publisher: Elsevier Science
Year: 2002
Tongue: English
Weight: 570 KB
Volume: 4
Category: Article
ISSN: 1293-2558
DOI: 10.1016/s1293-2558(02)00032-8

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The reaction between Nd(AsF 6 ) 3(solv) and excess of XeF 2(solv) in anhydrous HF (aHF) yields compounds of the type [Nd(XeF 2 ) n ] (AsF 6 ) 3 (n ‫؍‬ 3, 2.5). The 5rst compound is very soluble in aHF while the latter crystallizes from the saturated solution in aHF. Pink needles [Nd(XeF 2 ) 2.5 ] (A