Cationic η1/η2-Gold(I) Complexes of Simple Arenes
✍ Scribed by Elena Herrero-Gómez; Cristina Nieto-Oberhuber; Salomé López; Jordi Benet-Buchholz; Antonio M. Echavarren
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 326 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
The half-sandwich titanium trimethyl complex (η 5 -C 5 H 4 CMe 2 Ar)TiMe 3 (Ar = 3,5-Me 2 C 6 H 3 ) reacts with the Lewis acid B(C 6 F 5 ) 3 to give the ionic Ti IV ansa-cyclopentadienyl-arene complex [(η 5 ,η 6 -C 5 H 4 CMe 2 Ar)TiMe 2 ]-[MeB(C 6 F 5 ) 3 ]. In bromobenzene solvent, addition of more
During the last decade, supramolecular architecture in gold(i) chemistry has attracted growing attention owing to the aurophilic nature of gold and the rich luminescence properties that many gold(i) complexes exhibit. [1, 2] The majority of the work in this area has been focused on systems that invo
the ring (17)[71. These compounds were also no& identical with Dolastatin 3. The following characteristic differences in the NMR spectra of the 16 diastereomers and that of Dolastatin 3 were found: 1) Different chemical shift and coupling for the amide protons, 2) different chemical shift and coupli