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Cationic rhodium(I) and iridium(I) α-diimine complexes

✍ Scribed by Duncan A.J. Harding; Eric G. Hope; Kuldip Singh; Gregory A. Solan

Book ID
113856771
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
482 KB
Volume
33
Category
Article
ISSN
0277-5387

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Catalytic hydrogen transfer activity of
Catalytic hydrogen transfer activity of cationic iridium(I) complexes containing α-diimines
✍ Mohammed Bikrani; Luz Fidalgo; María A. Garralda; Carlos Ubide 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 619 KB

## Cationic [Ir(COD)(LL)]+ species (LL = cr-diimines derived from biacetyl or glyoxal) in the presence of KOH are active catalysts in the homogeneous hydrogen transfer from isopropanol to acetophenone to give phenylethanol. The most active species is the cation containing biacetyloximehydrazone.