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Cationic RhI Complexes of Azulenes and Their Catalytic Activity on the Formation of Heptalene-1,2-dicarboxylates from Dimethyl Acetylenedicarboxylate and Azulenes

✍ Scribed by Andreas Johannes Rippert; Anthony Linden; Hans-Jürgen Hansen


Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
703 KB
Volume
76
Category
Article
ISSN
0018-019X

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✦ Synopsis


Part of planned Ph. D. thesis of A . J . R., University of Zurich ')

At a temperature where the exchange process is slow, four signals for the olefinic H-atoms should be observable. The symmetric complex 3g in CD,CI, at -60" shows, indeed, two broad signals at 4.20 and 4.28 ppm for the olefinic H-atoms of the cod ligand.