Cationic rearrangement of a seco-homocubanone to a brendanone and a pentalenone

✍ Scribed by P.J.D. Sakkers; J.M.J. Vankan; A.J.H. Klunder; B. Zwanenburg

• Book ID: 104244697
• Publisher: Elsevier Science
• Year: 1979
• Tongue: French
• Weight: 273 KB
• Volume: 20
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)93582-8

✦ Synopsis

Bridgehead alcohols in strained cage systems such as homocuban-4-01s and 1,3-bishomocuban-5-01s readily undergo regio-and stereospecific homoketoniaation reactions under basic conditions I,2 . Recently, we found that homocuban-4-