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Cationic polypyrrole matrix and its functional composites with anionic metal complexes

✍ Scribed by T. Iyoda; M. Aiba; T. Saika; T. Shimidzu


Publisher
Elsevier Science
Year
1991
Weight
134 KB
Volume
15
Category
Article
ISSN
0923-1137

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✦ Synopsis


term 'hydroxy-phlorin' is used for the designation of the product in order to distinguish it from normal phlorin and isoporphyrin.) Although the hydroxy-phlorin was stable for near-infrared light, it was isomaiized by visible-light irradiation under anaerobic conditions. The wavelength selective photoreaction is suitable for the design of a material which will have photo-responsibility for the writing visible light and photo-stability for the readout near-infrared light.

In a similar manner, cationic gold porphyrins formed hydroxy-phlorins. The hydroxy-phlorins fixed in an anionic polymer matrix were also photo-responsible to visible light irradiation.


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