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Cationic polymerization of tetrahydrofuran initiated by difunctional initiators. Synthesis of block copolymers

✍ Scribed by Baki Hazer


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
216 KB
Volume
26
Category
Article
ISSN
0014-3057

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✦ Synopsis


Abstract~Cationic polymerization of tetrahydrofuran (THF) initiated by difunctional peroxidic initiators bis(4-bromomethyl benzoyl) peroxide and 2,5-dimethyl 2,5-di(4-bromomethyl benzoyl peroxy)hexane is described. Poly-THF samples possessing peroxidie groups thus obtained were used in the polymerization of styrene at 80 Β° to obtain THF-styrene block copolymers in high yields.


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Cationic polymerization of isobutylene p
✍ Miroslav Marek; Jan Pecka; Vlastimil HalaΕ‘ka πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 262 KB

## Abstract The cationic polymerization of isobutylene with weak Lewis acids, such as BBr~3~ and FeBr~3~, has been studied. These halides are unable to induce individually the polymerization in nonpolar solvents, such as heptane or toluene, or they only initiate the polymerization to low conversion