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Cationic polymerization of 6,8-dioxa-bicyclo(3.2.1)octane

✍ Scribed by Sumitomo, Hiroshi ;Okada, Masahiko ;Hibino, Yasuo

Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
219 KB
Volume
10
Category
Article
ISSN
0449-2986

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New methodology for the synthesis of enantiopure 3-aza-6,8-dioxa-bicyclo[3.2.1]octane-carboxylic acids belonging to 7-endo-BTAa sub-class of g/d amino acids is described. The novelty is the use of 2,3-O-isopropylidene-erythrose instead of meso-tartaric acid derivative, thus allowing us to perform an