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Cationic polymerization of 2-vinylthiophene - the polymer structure formation

✍ Scribed by Susanne Höhne; Stefan Spange; Wolfgang Schrepp


Publisher
Springer
Year
2001
Tongue
English
Weight
181 KB
Volume
47
Category
Article
ISSN
0170-0839

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## Abstract Glycidol (2‐epoxy‐1‐propanol) was polymerized under the action of Lewis acids (BF~3~OEt~2,~, SnCl~4~) and protonic acids (CF~3~COOH, CF~3~SO~3~H). Polymers with number‐average molecular weights (__M̄__~n~) varying from 2500 to 6000 g/mol were obtained. The structure of obtained polymers

Cationic Polymerization of 2-Vinylthioph
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## Abstract **Summary:** 2‐Vinylthiophene (2‐VT) has been cationically polymerized using chloroarylmethane derivatives as the surface polymerization initiator on silica. By applying this procedure a soluble fraction of poly(vinylthiophene) (PVT) and PVT/silica composites can be simultaneously synth